35.1 Product Class 1: One Saturated Carbon—Chlorine Bond 35.1.1 Product Subclass 1: Chloroalkanes 35.1.1.1 Synthesis by Substitution of Hydrogen 35.1.1.2 Synthesis by Substitution of Metals 35.1.1.3 Synthesis by Substitution of Carbon Functionalities 35.1.1.4 Synthesis by Substitution of Other Halogens 35.1.1.5 Synthesis by Substitution of Oxygen Functionalities 35.1.1.6 Synthesis by Substitution of Sulfur, Selenium, or Tellurium Functionalities 35.1.1.7 Synthesis by Substitution of Nitrogen Functionalities 35.1.1.8 Synthesis by Addition to π-Type C—C Bonds 35.1.1.9 Synthesis from Other Chlorine Compounds 35.1.2 Product Subclass 2: Propargylic Chlorides 35.1.3 Product Subclass 3: Benzylic Chlorides 35.1.3.1 Synthesis by Substitution of Hydrogen 35.1.3.2 Synthesis by Substitution of Carbonyl Oxygen 35.1.3.3 Synthesis by Substitution of σ-Bonded Heteroatoms 35.1.4 Product Subclass 4: Allylic Chlorides 35.1.4.1 Synthesis by Substitution of Hydrogen α to a C=C Bond 35.1.4.2 Synthesis by Substitution of σ-Bonded Heteroatoms 35.1.5 Product Subclass 5: 1-Chloro-n-Heteroatom-Functionalized Alkanes (n ≥2) with Both Functions Formed Simultaneously 35.1.5.1 Synthesis by Addition across C=C Bonds 35.1.5.2 Synthesis by Addition across C—O Bonds 35.1.5.3 Synthesis by Addition across C—S Bonds 35.1.5.4 Synthesis by Addition across C—N Bonds 35.1.5.5 Synthesis by Addition across C—C Bonds 35.2 Product Class 2: One Saturated Carbon—Bromine Bond 35.2.1 Product Subclass 1: Bromoalkanes 35.2.1.1 Synthesis by Substitution of Hydrogen 35.2.1.2 Synthesis by Substitution of Metals 35.2.1.3 Substitution of Carbon Functionalities 35.2.1.4 Synthesis by Substitution of Other Halogens 35.2.1.5 Synthesis by Substitution of Oxygen Functionalities 35.2.1.6 Synthesis by Substitution of Sulfur, Selenium, or Tellurium Functionalities 35.2.1.7 Synthesis by Substitution of Nitrogen Functionalities 35.2.1.8 Synthesis by Addition to π-Type C—C Bonds 35.2.1.9 Synthesis from Other Bromo Compounds 35.2.2 Product Subclass 2: Propargylic Bromides 35.2.3 Product Subclass 3: Benzylic Bromides 35.2.3.1 Synthesis by Substitution of Hydrogen 35.2.3.2 Synthesis by Substitution of Carbonyl Oxygen 35.2.3.3 Synthesis by Substitution of σ-Bonded Heteroatoms 35.2.4 Product Subclass 4: Allylic Bromides 35.2.4.1 Synthesis by Substitution of Hydrogen α to a C=C Bond 35.2.4.2 Synthesis by Substitution of σ-Bonded Heteroatoms 35.2.5 Product Subclass 5: 1-Bromo-n-Heteroatom-Functionalized Alkanes (n ≥2) with Both Functions Formed Simultaneously 35.2.5.1 Synthesis by Addition across C=C Bonds 35.2.5.2 Synthesis by Addition across C—O Bonds 35.2.5.3 Synthesis by Addition across C—S Bonds 35.2.5.4 Synthesis by Addition across C—N Bonds 35.2.5.5 Synthesis by Addition across C—C Bonds 35.3 Product Class 3: One Saturated Carbon—Iodine Bond 35.3.1 Product Subclass 1: Iodoalkanes 35.3.1.1 Synthesis by Substitution of Hydrogen 35.3.1.2 Synthesis by Substitution of Metals 35.3.1.3 Synthesis by Substitution of Carbon Functionalities 35.3.1.4 Synthesis by Substitution of Other Halogens 35.3.1.5 Synthesis by Substitution of Oxygen Functionalities 35.3.1.6 Synthesis by Substitution of Sulfur, Selenium, or Tellurium Functionalities 35.3.1.7 Synthesis by Substitution of Nitrogen Functionalities 35.3.1.8 Synthesis by Addition to π-Type C—C Bonds 35.3.1.9 Synthesis from Other Iodo Compounds 35.3.2 Product Subclass 2: Propargylic Iodides 35.3.3 Product Subclass 3: Benzylic Iodides 35.3.3.1 Synthesis by Substitution of Carbonyl Oxygen 35.3.3.2 Substitution of σ-Bonded Heteroatoms 35.3.4 Product Subclass 4: Allylic Iodides 35.3.5 Product Subclass 5: 1-Iodo-n-Heteroatom-Functionalized Alkanes (n ≥2) with Both Functions Formed Simultaneously 35.3.5.1 Synthesis by Addition across C=C Bonds 35.3.5.2 Synthesis by Addition across C—O Bonds 35.3.5.3 Synthesis by Addition across C—S Bonds 35.3.5.4 Synthesis by Addition across C—N Bonds 35.3.5.5 Synthesis by Addition across C—C Bonds