Iodine Catalysis in Organic Synthesis The first book of its kind to highlight iodine as a sustainable alternative to conventional transition metal catalysis Iodine Catalysis in Organic Synthesis provides detailed coverage of recent advances in iodine chemistry and catalysis, focusing on the utilization of various iodine-containing compounds as oxidative catalysts. Featuring contributions by an international panel of leading research chemists, this authoritative volume explores the development of environmentally benign organic reactions and summarizes catalytic transformations of molecular iodine and iodine compounds such as hypervalent organoiodine and inorganic iodine salts. Readers are first introduced to the history of iodine chemistry, the conceptual background of homogeneous catalysis, and the benefits of iodine catalysis in comparison with transition metals. Next, chapters organized by reaction type examine enantioselective transformations, catalytic reactions involving iodine, catalyst states, oxidation in iodine and iodine catalyses, and catalytic reactions based on halogen bonding. Practical case studies and real-world examples of different applications in organic synthesis and industry are incorporated throughout the text. An invaluable guide for synthetic chemists in both academic and industrial laboratories, Iodine Catalysis in Organic Synthesis: Provides a thorough overview of typical iodine-catalyzed reactions, catalyst systems, structures, and reactivityExplores promising industrial applications of iodine-based reagents for organic synthesis Highlights the advantages iodine catalysis has over classical metal-catalyzed reactionsDiscusses sustainable and eco-friendly methods in hypervalent iodine chemistry Edited by two world authorities on the catalytic applications of organoiodine compounds, Iodine Catalysis in Organic Synthesis is required reading for catalytic, organic, and organometallic chemists, medicinal and pharmaceutical chemists, industrial chemists, and academic researchers and advanced students in relevant fields.
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Preface xi 1 Historical Introduction 1 Viktor V. Zhdankin 2 Concepts in Iodine Catalysis 11 Kazuaki Ishihara 3 Catalysis by Halogen Bonding Based on Iodine 27 Revannath L. Sutar and Stefan M. Huber 4 Catalytic Transformations with R4NI Catalyst Precursors 69 Xiao-Xian Li and Yun-Fei Du 5 Catalytic Transformations Based on Iodine(I) Involving Radical Pathways 121 Alexandra E. Bosnidou and R. Martin Romero 6 Aromatic C–H Functionalization 151 Mahesh Puthanveedu and Andrey P. Antonchick 7 Design of Chiral Organoiodine(I/III) Catalysts for Asymmetric Oxidative Transformations 185 Andreas Boelke and Boris J. Nachtsheim 8 Catalytic and Asymmetric Dearomatization Reactions Employing Hypervalent Iodine Reagents 211 Toshifumi Dohi and Yasuyuki Kita 9 Catalytic Alkene Difunctionalization Reactions 243 John M. Ovian and Eric N. Jacobsen 10 Catalytic Oxidative 𝛂-Functionalization of Carbonyls 275 Muhammet Uyanik 11 Oxidations with Iodine(V) Compounds – From Stoichiometric Compounds to Catalysts 299 Frederic Ballaschk and Stefan F. Kirsch 12 Sustainable Methods in Hypervalent Iodine Chemistry 335 Brandon Frey, Asim Maity, Hao Tan, Pritam Roychowdhury, and David C. Powers 13 Industrial Application of Iodine Catalysis 387 Tatsuo Kaiho References 412 Index 415
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The first book of its kind to highlight iodine as a sustainable alternative to conventional transition metal catalysis Iodine Catalysis in Organic Synthesis provides detailed coverage of recent advances in iodine chemistry and catalysis, focusing on the utilization of various iodine-containing compounds as oxidative catalysts. Featuring contributions by an international panel of leading research chemists, this authoritative volume explores the development of environmentally benign organic reactions and summarizes catalytic transformations of molecular iodine and iodine compounds such as hypervalent organoiodine and inorganic iodine salts. Readers are first introduced to the history of iodine chemistry, the conceptual background of homogeneous catalysis, and the benefits of iodine catalysis in comparison with transition metals. Next, chapters organized by reaction type examine enantioselective transformations, catalytic reactions involving iodine, catalyst states, oxidation in iodine and iodine catalyses, and catalytic reactions based on halogen bonding. Practical case studies and real-world examples of different applications in organic synthesis and industry are incorporated throughout the text. An invaluable guide for synthetic chemists in both academic and industrial laboratories, Iodine Catalysis in Organic Synthesis: Provides a thorough overview of typical iodine-catalyzed reactions, catalyst systems, structures, and reactivityExplores promising industrial applications of iodine-based reagents for organic synthesis Highlights the advantages iodine catalysis has over classical metal-catalyzed reactionsDiscusses sustainable and eco-friendly methods in hypervalent iodine chemistry Edited by two world authorities on the catalytic applications of organoiodine compounds, Iodine Catalysis in Organic Synthesis is required reading for catalytic, organic, and organometallic chemists, medicinal and pharmaceutical chemists, industrial chemists, and academic researchers and advanced students in relevant fields.
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Produktdetaljer

ISBN
9783527348299
Publisert
2022-02-02
Utgiver
Vendor
Blackwell Verlag GmbH
Vekt
992 gr
Høyde
244 mm
Bredde
170 mm
Dybde
26 mm
Aldersnivå
P, 06
Språk
Product language
Engelsk
Format
Product format
Innbundet
Antall sider
448

Om bidragsyterne

Kazuaki Ishihara is Full Professor, Nagoya University, Japan. He serves on the editorial advisory boards of European Journal of Organic Chemistry, Asian Journal of Organic Chemistry, and Topics in Current Chemistry. He is the author of Acid Catalysis in Modern Organic Synthesis and has published more than 350 articles in international journals.

Kilian Muñiz was ICREA Research Professor and Group Leader, Institute of Chemical Research of Catalonia (ICIQ), Tarragona, Spain. He was Vice-President of the Organic Section of the Royal Spanish Society of Chemistry and served on the advisory boards of Advanced Synthesis and Catalysis, The Chemical Record, and ACS Journal of Organic Chemistry. Professor Kilian Muñiz passed away unexpectedly in March 2020.