"This book continues the high standard of <i>The Chemistry of Functional Groups</i> series and is an essential resource for professional organic and inorganic chemists and their research groups who have an interest in organometallic chemistry. It could also prove useful in postgraduate teaching for designing a modern course on the subject. With the recent report of the first crystallographically characterized Mg - Mg bonded compound, this area is likely to increase in popularity and research activity; thus, the publication of this book is timely. A copy should be made available in every library that houses a section on advanced chemistry at the postgraduate level and above." (<i>Journal of the American Chemical Society</i>, November 12, 2008)

Magnesium remains almost unique among the metals in its ability to react directly with a wide variety of compounds. This organic chemistry field has seen steady progress, and a volume on this topic is long overdue.  In the tradition of the Patai Series this title treats all aspects of functional groups, containing chapters on the theoretical and computational foundations; on analytical and spectroscopic aspects with dedicated chapters on Mass Spectrometry, NMR, IR/UV, etc.; on reaction mechanisms; on applications in syntheses. Depending on the functional group there are also chapters on industrial use, on effects in biological and/or environmental systems. Since the area of Organomagnesium Chemistry continues to grow far beyond the classical Grignard Reagents, this is an essential resource to help the reader keep abreast of the latest developments.
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The Chemistry of Organomagnesium Compounds, the newest volume in the critically acclaimed Patai Series, explores the compound of Magnesium. The field has seen steady progress, and a volume on this topic has long been overdue.
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1. Structural organomagnesium chemistry (Johann T.B.H. Jastrzebski, Jaap Boersma and Gerard van Koten). 2. The thermochemistry of organomagnesium compounds (Joel F. Liebman, Torkil Holm and Suzanne W. Slayden). 3. NMR of organomagnesium compounds (Peter J. Heard). 4. Formation, chemistry and structure of organomagnesium species in solvent-free environments (Richard A. J. O'Hair). 5. Photochemical transformations involving magnesium porphyrins and phthalocyanines (Natalia N. Sergeeva and Mathias O. Senge). 6. Electrochemistry of organomagnesium compounds (Jan S. Jaworski). 7. Analytical aspects of organomagnesium compounds (Jacob Zabicky). 8. Biochemistry of magnesium (James Weston). 9. Theoretical studies of the addition of RMgX to carbonyl compounds (Shinichi Yamabe and Shoko Yamazaki). 10. Organomagnesium-group 15-and Organomagnesium-group 16-bonded complexes (Katherine L. Hull and Kenneth W. Henderson). 11. Preparation and reactivity of Magnesium enolates (Claude Grison). 12. Functionalized organomagnesium compounds: Synthesis and reactivity (Paul Knochel, Andrey Gavryushin and Katja Brade). 13. Iron-Catalyzed reactions of Grignard Reagents (Gérard Cahiez and Christophe Duplais). 14. Carbomagnesiation reactions (Kenichiro Itami and Jun-ichi Yoshida). 15. The chemistry of organomagnesium ate complexes (Hideki Yorimitsu and Koichiro Oshima). 16. The chemistry of magnesium carbenoids (Tsuyoshi Satoh). 17. Catalytic enantioselective conjugate addition and allylic alkylation reactions using Grignard reagents (Fernando López, Adriaan J. Minnaard and Ben L. Feringa). Author Index. Subject Index.
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Patai Series: The chemistry of Organomagnesium Compounds. A series of advanced treatises founded by Professor Saul Patai and under the general editorship of Professor Zvi Rappoport The Patai Series publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopic methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical and environmental aspects. To date, over 110 volumes have been published in the series. Recently Published Titles: The chemistry of the Cyclopropyl Group (Volume 2) The chemistry of the Hydrazo, Azo and Azoxy Groups (Volume 2, 2 parts) The chemistry of Double-Bonded Functional Groups (Volume 3, 2 parts) The chemistry of Organophosphorus Compounds (Volume 4) The chemistry of Halides, Pseudo-Halides and Azides (Volume 2, 2 parts) The chemistry of the Amino, Nitro and Nitroso Groups (2 volumes, 2 parts) The chemistry of Dienes and Polyenes (2 volumes) The chemistry of Organic derivatives of Gold and Silver The chemistry of Organic Silicon Compounds (2 volumes, 4 parts) The chemistry of Organic Germanium, Tin and Lead Compounds (Volume 2, 2 parts) The chemistry of Phenols (2 parts) The chemistry of Organolithium Compounds (2 volumes, 3 parts) The chemistry of Cyclobutanes (2 Parts) The chemistry of peroxides (Volume 2, 2 parts) The chemistry of Organozinc Compounds (2 parts) The chemistry of Anilines (2 parts) Forthcoming Titles: The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids The Chemistry of Metal Enolates The Patai Series Online. the Patai Series is available in electronic format on Wiley InterScience. All new titles will be published as online books and a growing list of older titles will be added every year. It is the ultimate goal that all titles published in the Patai Series will be available in electronic format.  For more information see under Online Books on: www.interscience .wiley.com
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Produktdetaljer

ISBN
9780470057193
Publisert
2008-02-29
Utgiver
Vendor
John Wiley & Sons Inc
Vekt
1616 gr
Høyde
239 mm
Bredde
159 mm
Dybde
61 mm
Aldersnivå
P, 06
Språk
Product language
Engelsk
Format
Product format
Innbundet
Antall sider
920

Om bidragsyterne

Professor Zvi Rappoport, Department of Organic Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel.

Ilan Marek is Professor of Chemistry at the Technion - Israel Institute of Technology. He was educated in France and received his PhD thesis in 1988 from the University Pierre et Marie Curie, Paris. He has been visiting Professor at the University de Montreal (Canada); University of Strasbourg (France); University Paris-Descartes (France); California Institute of Technology (USA) and at the Ecole Nationale Superieure de Chimie de Montpellier (France). He was a member of the International Scientific Committee of the European Symposium on Organic Chemistry (ESOC), including the position of Chairman (2007-2009) and is currently the chairman of the division of organic chemistry, European Association of Chemical and Molecular Sciences (EuCheMS).